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合成フッ素マイカ層間に固定化したイミノピリジン鉄錯体による原子移動型ラジカル重合《マイレビュー》
https://doi.org/10.24561/00014504
https://doi.org/10.24561/00014504fd3b59fa-1237-4a71-9f9a-97133a79f0b2
名前 / ファイル | ライセンス | アクション |
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KY-AA12504266-01-16.pdf (328.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2011-02-01 | |||||
タイトル | ||||||
タイトル | 合成フッ素マイカ層間に固定化したイミノピリジン鉄錯体による原子移動型ラジカル重合《マイレビュー》 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014504 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Atom Transfer Radical Polymerization of methyl methacrylate using iminopyrdineiron complexes immobilized into fluorotetrasilicic mica interlayer | |||||
著者 |
近藤, 隆司
× 近藤, 隆司× 大嶋, 正明× 黒川, 秀樹× 三浦, 弘 |
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著者 ローマ字 | ||||||
KONDO, Takashi | ||||||
著者 ローマ字 | ||||||
OHSHIMA, Masa-aki | ||||||
著者 ローマ字 | ||||||
KUROKAWA, Hideki | ||||||
著者 ローマ字 | ||||||
MIURA, Hiroshi | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 1, p. 46-49, 発行日 2010 |
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年月次 | ||||||
2010-12 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学総合研究機構科学分析支援センター | |||||
出版者名(別言語) | ||||||
出版者 | Comprehensive Analysis Center for Science, Saitama University | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The iminopyridine iron(III) and (II) complexes were immobilized into fluorotetrasilicic mica interlayers through the intercalation of the iminopyridine ligand into the mica interlayers and simultaneous coordination of the ligand to the interlayer metal cations. The prepared catalysts were used for atom- transfer radical polymerization (ATRP) of methyl methacrylate (MMA). The Fe3+-based catalyst did not show a significant activity for the ATRP of MMA, whereas when ATRP was performed using the Fe2+-based catalyst, PMMA (poly(methyl methacrylate)) was obtained. Two peaks were observed in the GPC curve of the produced PMMA. Because polydispersity index was higher than 2, free-radical polymerization occurred simultaneously. To suppress the free-radical polymerization, we varied initiator/catalyst molar ratio. On increasing the molar ratio from 2/1 to 4/1 (favorable conditions for free-radical polymerization), PMMA with higher Mw was obtained. In contrast, by decreasing the molar ratio from 2/1 to 1/1 (favorable conditions for ATRP), PMMA with lower Mw was obtained. Those results clearly indicate that the lower Mw peak in the GPC curve corresponds to PMMA produced by ATRP. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2011-02-01 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AA12504266-01-16 |