WEKO3
アイテム
{"_buckets": {"deposit": "ba1f50a2-a94c-497d-82da-be9e984692b9"}, "_deposit": {"created_by": 3, "id": "16474", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "16474"}, "status": "published"}, "_oai": {"id": "oai:sucra.repo.nii.ac.jp:00016474", "sets": ["630"]}, "author_link": ["26668", "26669", "18298", "26667", "18381", "26670"], "item_120_alternative_title_1": {"attribute_name": "タイトル(別言語)", "attribute_value_mlt": [{"subitem_alternative_title": "Study on the Effective and Selective Synthetic Reaction with Transition Metal Catalysts"}]}, "item_120_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2009", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "32", "bibliographicPageStart": "30", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "埼玉大学地域オープンイノベーションセンター紀要"}, {"bibliographic_title": "Report of Comprehensive Open Innovation Center, Saitama University", "bibliographic_titleLang": "en"}]}]}, "item_120_date_31": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2009-08-18", "subitem_date_issued_type": "Created"}]}, "item_120_description_19": {"attribute_name": "概要", "attribute_value_mlt": [{"subitem_description": "The oxidative addition of [Pt(2-nb)(PPh3)2] with a sterically hindered thiol TripSH (Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) Pt(II) complex PtH(Strip)(PPh3)2 as thermally and moisture stable colorless crystals in 91% yield. The thermal reaction of PtH(Strip)(PPh3)2 gave the corresponding thiaplatinacycle. The first stable dihydrogermyl(hydrido) platinum(II) complex PtH(GeH2Trip)(Ph3P)2 was synthesized by the oxidative addition reaction of TripGeH3 with Pt( 2-C2H4)(Ph3P)2 in toluene. The reaction of TripGeH3 with (dppe)PtCl2 in the presence of NaBH4 afforded the corresponding hydrido complex PtH(GeH2Trip)(dppe) together with bis(germyl) platinum(II) complex Pt(GeH2Trip)2(dppe). The ligand exchange reaction of PtH(GeH2Trip)(Ph3P)2 with Cy2PCH2CH2PCy2 (DCPE) in toluene resulted in the formation of PtH(GeH2Trip)(dcpe) in the moderate yield. Thermal rearrangement of Pt(GeH2Trip)2(dppe) in toluene at 60 ˚C gave digermyl(hydrido) complex PtH[Ge(Htrip)GeH2Trip](dppe) in high yield.", "subitem_description_type": "Other"}]}, "item_120_description_29": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_description": "text", "subitem_description_type": "Other"}]}, "item_120_description_30": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_120_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24561/00016468", "subitem_identifier_reg_type": "JaLC"}]}, "item_120_other_language_22": {"attribute_name": "その他の言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_120_publisher_11": {"attribute_name": "出版者名", "attribute_value_mlt": [{"subitem_publisher": "埼玉大学総合研究機構地域オープンイノベーションセンター"}]}, "item_120_relation_7": {"attribute_name": "著者 外部リンク", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/sxUesZBx"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/sxUesZBx", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/FxMKkSoS"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/FxMKkSoS", "subitem_relation_type_select": "URI"}}]}, "item_120_source_id_14": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "18838278", "subitem_source_identifier_type": "ISSN"}]}, "item_120_text_27": {"attribute_name": "版", "attribute_value_mlt": [{"subitem_text_value": "[出版社版]"}]}, "item_120_text_3": {"attribute_name": "著者 ローマ字", "attribute_value_mlt": [{"subitem_text_value": "Ishii, Akihiko"}, {"subitem_text_value": "Nakata, Norio"}, {"subitem_text_value": "Ashida, Takeshi"}, {"subitem_text_value": "Kato, Jun-ichi"}, {"subitem_text_value": "Arai, Teruaki"}, {"subitem_text_value": "Mori, Sayaka"}]}, "item_120_text_32": {"attribute_name": "アイテムID", "attribute_value_mlt": [{"subitem_text_value": "KY-18838278-12"}]}, "item_120_text_35": {"attribute_name": "公開日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Aug 18, 2009 11:28:34"}]}, "item_120_text_36": {"attribute_name": "記録日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "2009-08-18"}]}, "item_120_text_37": {"attribute_name": "最終更新日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Sep 6, 2009 18:43:59"}]}, "item_120_text_38": {"attribute_name": "公開日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Aug 18, 2009 11:28:34"}]}, "item_120_text_39": {"attribute_name": "更新履歴(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Sep 6, 2009 年 を変更"}, {"subitem_text_value": "Aug 21, 2009 インデックス, 著者 を変更"}, {"subitem_text_value": "Aug 19, 2009 インデックス, 抄録 を変更"}, {"subitem_text_value": "Aug 18, 2009 フリーキーワード, インデックス, 抄録 を変更"}]}, "item_120_text_4": {"attribute_name": "著者 所属", "attribute_value_mlt": [{"subitem_text_value": "埼玉大学大学院理工学研究科"}, {"subitem_text_value": "埼玉大学大学院理工学研究科"}, {"subitem_text_value": "株式会社ハイテック"}, {"subitem_text_value": "株式会社ハイテック"}, {"subitem_text_value": "株式会社ハイテック"}, {"subitem_text_value": "株式会社ハイテック"}]}, "item_120_text_40": {"attribute_name": "登録者(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "sucra_jim4"}]}, "item_120_text_41": {"attribute_name": "閲覧数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "956"}]}, "item_120_text_42": {"attribute_name": "ダウンロード数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "1436"}]}, "item_120_text_43": {"attribute_name": "XooNIps_インデックス", "attribute_value_mlt": [{"subitem_text_value": "sucra_jim4|Public/ジャンル別/研究紀要/埼玉大学/地域オープンイノベーションセンター紀要|Public/埼玉大学/理工学研究科|Public/埼玉大学/理工学研究科/物質科学部門|Public/主題別/化学/複合化学/合成化学"}]}, "item_120_text_44": {"attribute_name": "XooNIps_ITEM_KEY", "attribute_value_mlt": [{"subitem_text_value": "4672"}]}, "item_120_text_5": {"attribute_name": "著者 所属(別言語)", "attribute_value_mlt": [{"subitem_text_value": "Graduate School of Science and Engineering, Saitama University"}, {"subitem_text_value": "Graduate School of Science and Engineering, Saitama University"}, {"subitem_text_value": "Hitec Co., Ltd"}, {"subitem_text_value": "Hitec Co., Ltd"}, {"subitem_text_value": "Hitec Co., Ltd"}, {"subitem_text_value": "Hitec Co., Ltd"}]}, "item_120_text_9": {"attribute_name": "年月次", "attribute_value_mlt": [{"subitem_text_value": "2008"}]}, "item_120_version_type_28": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "石井, 昭彦"}], "nameIdentifiers": [{"nameIdentifier": "18298", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "sxUesZBx", "nameIdentifierScheme": "研究者総覧", "nameIdentifierURI": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/sxUesZBx"}]}, {"creatorNames": [{"creatorName": "中田, 憲男"}], "nameIdentifiers": [{"nameIdentifier": "18381", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "FxMKkSoS", "nameIdentifierScheme": "研究者総覧", "nameIdentifierURI": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/FxMKkSoS"}]}, {"creatorNames": [{"creatorName": "芦田, 彪"}], "nameIdentifiers": [{"nameIdentifier": "26667", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "加藤, 淳一"}], "nameIdentifiers": [{"nameIdentifier": "26668", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "新井, 輝明"}], "nameIdentifiers": [{"nameIdentifier": "26669", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "森, さやか"}], "nameIdentifiers": [{"nameIdentifier": "26670", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-01-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KY-18838278-12.pdf", "filesize": [{"value": "329.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 329400.0, "url": {"label": "KY-18838278-12.pdf", "url": "https://sucra.repo.nii.ac.jp/record/16474/files/KY-18838278-12.pdf"}, "version_id": "98e7dc39-5f88-45ec-8853-5703028116e8"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Platinum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Sulfur", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Germanium", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydrido complex", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Metallacycle", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "遷移金属錯体触媒を用いる効率的・選択的合成反応の研究", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "遷移金属錯体触媒を用いる効率的・選択的合成反応の研究"}]}, "item_type_id": "120", "owner": "3", "path": ["630"], "permalink_uri": "https://doi.org/10.24561/00016468", "pubdate": {"attribute_name": "公開日", "attribute_value": "2009-08-18"}, "publish_date": "2009-08-18", "publish_status": "0", "recid": "16474", "relation": {}, "relation_version_is_last": true, "title": ["遷移金属錯体触媒を用いる効率的・選択的合成反応の研究"], "weko_shared_id": 3}
遷移金属錯体触媒を用いる効率的・選択的合成反応の研究
https://doi.org/10.24561/00016468
https://doi.org/10.24561/000164680731a119-5669-457d-ba3b-0308fa5cd1b0
名前 / ファイル | ライセンス | アクション |
---|---|---|
KY-18838278-12.pdf (329.4 kB)
|
|
Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2009-08-18 | |||||
タイトル | ||||||
タイトル | 遷移金属錯体触媒を用いる効率的・選択的合成反応の研究 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Platinum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Sulfur | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Germanium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Hydrido complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Metallacycle | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00016468 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Study on the Effective and Selective Synthetic Reaction with Transition Metal Catalysts | |||||
著者 |
石井, 昭彦
× 石井, 昭彦× 中田, 憲男× 芦田, 彪× 加藤, 淳一× 新井, 輝明× 森, さやか |
|||||
著者 ローマ字 | ||||||
Ishii, Akihiko | ||||||
著者 ローマ字 | ||||||
Nakata, Norio | ||||||
著者 ローマ字 | ||||||
Ashida, Takeshi | ||||||
著者 ローマ字 | ||||||
Kato, Jun-ichi | ||||||
著者 ローマ字 | ||||||
Arai, Teruaki | ||||||
著者 ローマ字 | ||||||
Mori, Sayaka | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属 | ||||||
株式会社ハイテック | ||||||
著者 所属 | ||||||
株式会社ハイテック | ||||||
著者 所属 | ||||||
株式会社ハイテック | ||||||
著者 所属 | ||||||
株式会社ハイテック | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Hitec Co., Ltd | ||||||
著者 所属(別言語) | ||||||
Hitec Co., Ltd | ||||||
著者 所属(別言語) | ||||||
Hitec Co., Ltd | ||||||
著者 所属(別言語) | ||||||
Hitec Co., Ltd | ||||||
書誌情報 |
埼玉大学地域オープンイノベーションセンター紀要 en : Report of Comprehensive Open Innovation Center, Saitama University 巻 1, p. 30-32, 発行日 2009 |
|||||
年月次 | ||||||
2008 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学総合研究機構地域オープンイノベーションセンター | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18838278 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The oxidative addition of [Pt(2-nb)(PPh3)2] with a sterically hindered thiol TripSH (Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) Pt(II) complex PtH(Strip)(PPh3)2 as thermally and moisture stable colorless crystals in 91% yield. The thermal reaction of PtH(Strip)(PPh3)2 gave the corresponding thiaplatinacycle. The first stable dihydrogermyl(hydrido) platinum(II) complex PtH(GeH2Trip)(Ph3P)2 was synthesized by the oxidative addition reaction of TripGeH3 with Pt( 2-C2H4)(Ph3P)2 in toluene. The reaction of TripGeH3 with (dppe)PtCl2 in the presence of NaBH4 afforded the corresponding hydrido complex PtH(GeH2Trip)(dppe) together with bis(germyl) platinum(II) complex Pt(GeH2Trip)2(dppe). The ligand exchange reaction of PtH(GeH2Trip)(Ph3P)2 with Cy2PCH2CH2PCy2 (DCPE) in toluene resulted in the formation of PtH(GeH2Trip)(dcpe) in the moderate yield. Thermal rearrangement of Pt(GeH2Trip)2(dppe) in toluene at 60 ˚C gave digermyl(hydrido) complex PtH[Ge(Htrip)GeH2Trip](dppe) in high yield. | |||||
その他の言語 | ||||||
言語 | eng | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2009-08-18 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-18838278-12 |