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"2009-11-12"}, "publish_date": "2009-11-12", "publish_status": "0", "recid": "14919", "relation": {}, "relation_version_is_last": true, "title": ["カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果\u003c総説 レビュー\u003e"], "weko_shared_id": 3}
カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説 レビュー>
https://doi.org/10.24561/00014913
https://doi.org/10.24561/0001491316373c4b-807b-4ec8-a67e-65446ef1c2ed
名前 / ファイル | ライセンス | アクション |
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KY-AN10402595-22-02.pdf (420.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-11-12 | |||||
タイトル | ||||||
タイトル | カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説 レビュー> | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014913 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Electronic and Steric Effects of the Substituents on the Rate of Unidentate Exchange in Carboxylate-Bridged Trinuclear Metal Complexes | |||||
著者 |
藤原, 隆司
× 藤原, 隆司× 永澤, 明 |
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著者 ローマ字 | ||||||
FUJIHARA, Takashi | ||||||
著者 ローマ字 | ||||||
NAGASAWA, Akira | ||||||
著者 所属 | ||||||
埼玉大学理学部基礎化学科 | ||||||
著者 所属 | ||||||
埼玉大学理学部基礎化学科 | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Faculty of Science, Saitama University | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Faculty of Science, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 22, p. 2-9, 発行日 2002 |
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年月次 | ||||||
2002-12 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学分析センター | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The carboxylate-bridged trinuclear metal complex ions undergo the substitution of unidentate ligands (L) at the terminal sites, while the bridging carboxylato and the central m3-oxo ligands are inert (Type I: n = 1; M = Cr, Co, Ru, Rh. Type II: n = 2; M = Mo, W). [M3(m3-O)n(m-RCO2)6(L)3]m+ + 3 L' → [M3(m3-O)n(m-RCO2)6(L')3]m+ + 3L We have kinetically studied the substitution reactions for the terminal ligands in the complexes of Group 6 metals, and discussed the results in relevance to their structures to reveal the mutual ligand effects of the capping m3-oxide and the bridging carboxylates. |
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版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2009-11-18 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AN10402595-22-02 |